Since beryllium oxide is high stable, it makes BeCO 3 unstable. Weigh a test tube. Nitrates of group -1 and group-2 metals are all soluble in water. Even for hydroxides we have the same observations. The solubility of alkaline metal carbonates and sulphates decreases with decrease in hydration energy as we move down the group. The least soluble hydroxide in Group 1 is lithium hydroxide - but it is still possible to make a solution with a concentration of 12.8 g per 100 g of water at 20°C. This is why the solubility of Group 2 hydroxides increases while progressing down the group. This page looks at the solubility in water of the hydroxides, sulphates and carbonates of the Group 2 elements - beryllium, magnesium, calcium, strontium and barium. Hence, more is the stability of oxide formed, less will be stability of carbonates. Although it describes the trends, there isn't any attempt to explain them on this page - for reasons discussed later. The size of B e 2 + is smallest and the size of B a 2 + is highest. Place 2 g of a Group 2 metal carbonate in the test tube and reweigh. Looking at the enthalpy change of formation for group 2 metal oxides it’s clearly less energy is needed to break them as you go down the group. Hence, barium hydroxide is more soluble than beryllium hydroxide. (ii) All the alkaline earth metals form oxides of formula MO. The hydroxides of the Group II metals, which may be used in thermochemical water-splitting cycles, have been investigated thermoanalytically. Magnesium hydroxide: this is the most insoluble and can be brought as a suspension in water. The hydroxides. As the size increases, the decrease in the lattice energy is much more than the decrease in the hydration energy. Now let's look at $\ce{SO4^2-}$. Place the other end of the delivery tube into a test tube which is one third full of limewater. The thermal stability of the hydrogencarbonates. The increasing thermal stability of Group 2 metal salts is consistently seen. Correct option: (d) Ba(OH) 2 < Sr(OH) 2 < Ca(OH) 2 < Mg(OH) 2 Explanation: Stability of ionic compounds decreases with decrease in lattice enthalpy. Charge Density and Polarising Power of Group 2 Metal Cations. Stability of oxides decreases down the group. Decomposition temperatures and decomposition enthalpies of the four hydroxides increase with increasing atomic weight of the compounds. Thus stability of alkaline earth metal hydroxides decreases with decrease in lattice enthalpy as the size of alkali earth metal cations increases down the group. The same thing applies to the cation while progressing down the group. Thus stability of alkaline earth metal hydroxides decreases with decrease in lattice enthalpy as the size of alkali earth metal cations increases down the group. BeCO 3 ⇌ BeO + CO 2. So what causes this trend? The respective TG- and DSC-curves are represented. Let's use MgCO 3 as an example. There is no reaction or precipitate when dilute sodium hydroxide is added to a solution of Sr 2+ or Ba 2+ ions. ... Solubility of the carbonates increases as you go down Group 1. A higher temperature is required to decompose Ba(NO 3) 2 as compared to Mg(NO 3) 2. Solution: Stability of ionic compounds decreases with decrease in lattice enthalpy. (ii) Thermal stability Alkali and alkaline earth metal nitrates decompose on heating. Attach the delivery tube to the test tube. Alternative Thermal decomposition of group 2 carbonates practical. Sulphates: Thermal stability The sulphates of group-1 and group-2 metals are all thermally stable. solubility: sulphates of alkali metals are soluble in water. The solubilities of these salts further increase on descending the group. 2 M N O 3 h e a t 2 M n O 2 + O 2 On heating alkali metal (Na, K, Rb and Cs) decompose to form metal nitrites and oxygen. —————————————————— Uses of sulphate and hydroxides. 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